< Page:Scientific Papers of Josiah Willard Gibbs.djvu
This page has been proofread, but needs to be validated.

398

VAPOR-DENSITIES.

irregularity which is characteristic of errors of observation. We should expect large errors in the observed densities, on account of the difficulty of obtaining the substance in a state of purity, and because the large value of the density renders it very sensitive to the effect of impurities which diminish the density,—also because the specific heat of the vapor is great, as shown by the numerator of the fraction in the second member of (13),[1] and because the density varies very rapidly with the temperature as seen by the numbers in the third column of Table VIII.

Table VIII.—Perchloride of Phosphorus.
Experiments of Mitscherlich, Cahours, Wurtz, and Troost
and Hautefeuille.
TemperaturePressureDensity calculated
by eq. (13).
Density observed.Excess of observed density.
Mitscherlich.Cahours.Mitscherlich.Cahours.
336(760)3.6103.656+.046
3277543.6143.656+.042
3007653.6373.654+.017
289(760)3.6563.69+.034
2887633.6593.67+.011
2747553.7013.84+.139
2507513.8623.991+.129
2307464.1594.302+.142
2227534.3444.85+.506
208(760)4.7524.73-.021
2007585.0184.851-.167
1907585.3684.987-.381
1827575.6465.078-.568
Wurtz.T. & H.Wurtz.T. & H.
178.5227.25.0535.150+.097
167.6221.85.4565.235+.012
154.7221.85.9265.619-.041
150.12256.0865.886-.200
148.62446.1695.964-.205
1453916.456.55+.10
1453116.376.70+.33
1453076.366.33-.03
1453076.366.33-.03
144.72476.2876.14-.147
1372816.536.48-.05
1372696.516.54+.03
1372436.486.46-.02
1372346.476.42-.05
1371486.316.47+.16
1291916.596.18-.41
1291706.566.63+.07
1291656.556.31-.24

But at the two lowest temperatures of Cahours' experiments, the differences of the observed and calculated densities (.381 and .568) are not only great, but exhibit, in connection with the adjacent numbers, a regularity which suggests a very different law from that of the

  1. Compare Equilib. Het. Subs., this volume p. 180, and supra pp. 380–382.
This article is issued from Wikisource. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.