< Page:Elementary Principles in Statistical Mechanics (1902).djvu
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72
AVERAGE VALUES IN A CANONICAL
of these anomalies is of course zero. The natural measure of such anomalies is the square root of their average square. Now
identically. Accordingly
In like manner,
Hence
Equation (206) shows that the value of can never be negative, and that the value of or can never be positive.[1]
To get an idea of the order of magnitude of these quantities, we may use the average kinetic energy as a term of comparison, this quantity being independent of the arbitrary constant involved in the definition of the potential energy. Since
| (204) |
| (205) |
| (206) |
| (207) |
| (208) |
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In the case discussed in the note on page 54, in which the potential energy is a quadratic function of the 's, and independent of the 's, we should get for the potential energy
and for the total energyWe may also write in this case,
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