Descartes famously argued that we can technically be wrong about anything. We can even doubt that the world isn't actually real in some sense and is just a simulation. But why does doubt imply the possibility that you could be wrong? Isn't doubt just a psychological state?
What exactly makes it irrational to think you can't be wrong about a particular thing? For example, is it irrational to be certain of the fact that there is no God? Or to be certain that the sun isn't going to turn into a unicorn tomorrow? Is it irrational to not just assign something to be of a non zero, but a literally zero probability?
In Bayesianism, this is often defended against, by the notion that if you assign a zero probability to something, it means that no amount of evidence can change your belief. But shouldn't a non zero probability, even if infinitesimal, be justified as well? If I am assigning a non zero probability to something like the sun turning into a unicorn tomorrow, aren't I basically implying that there is a non zero chance that could happen? But what evidence do I have that it could? If I have none, how could I assign a non zero probability to a statement if I don't have any indication to suggest that it is possible in the first place?
Suppose I assert certainty in X. One can argue that my certainty is not rational simply because I can't prove that for sure since I may be wrong. But the very possibility of me being wrong is an assumption. What if I'm simply not wrong? Until and unless I've been shown that I'm wrong, there is no way to actually falsify that certainty. But if there is no way to falsify it, how can it be considered to be irrational?
Note that my question isn't about whether we should think we can't be wrong about everything, but whether it is rational to think that we can't be wrong with respect to certain things. Historical examples of thinking we can't be wrong with respect to X and having it turn out that we were wrong about it does not imply that we can be wrong about Y.