Supposed the breaker is off but the left side is still hot (let's say breaker defective). Won't it work if you measure the terminal in the hot right and load left like in the following picture?

Why won't it work (if it won't work)?
Original message:

I'll connect two chair lugs to the screws in the above 125A main breaker feeder cooper. If I shut down the main breaker, how do I check both hot wires are gone without any neutral (we don't use neutral since all our equipments are 240v)? A defective breaker may only disable one of the hots. If I use a multimeter, where will I put the other lead on for each?