x:y:z:$PATH or $PATH:x:y:z?
Barely different. $PATH contains a :-separated list of places where bash (the shell/terminal) should check for a program.
For example if you type cat the way the terminal understands what that means is to look through the first, second, third elements of $PATH, then save the first location it finds for later invocations of cat.
If I have two different versions of a program in two different places, with one of them being preferred, and $PATH tells the shell to search in the wrong order, then there's a problem. Otherwise, no problem.
export
Open a terminal and type
echo $a
a=5
echo a
echo $a
You'll see that a=5 set the variable value and $a refers to the variable name, not the value.
Open a second terminal and type echo $a. It should again be blank.
The difference between export and assignment (=) is explained here: https://stackoverflow.com/questions/1158091/defining-a-variable-with-or-without-export.