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This may be called the probability of the petit ensemble . The sum of all such probabilities is evidently unity. That is,
which agrees with (506).
If is a function of alone, i. e., if it has the same value in all systems of any same petit ensemble, the formula reduces to
Again, if we write and to distinguish averages in the grand and petit ensembles, we shall have
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SYSTEMS COMPOSED OF MOLECULES.
| (516) |
| (517) |
| (518) |
The average value in the grand ensemble of any quantity , is given by the formula
| (519) |
| (520) |
| (521) |
In this chapter, in which we are treating of grand ensembles, will always denote the average for a grand ensemble. In the preceding chapters, has always denoted the average for a petit ensemble.
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