< Page:Elementary Principles in Statistical Mechanics (1902).djvu
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MAXIMUM AND MINIMUM PROPERTIES.
of the probability-coefficients of the original ensembles, the average index of probability of the resulting ensemble cannot be greater than the same linear function of the average indices of the original ensembles. It can be equal to it only when the original ensembles are similarly distributed in phase.
where
The main proposition to be proved is that
or
will be positive, except when it vanishes for . To prove this, we may regard and as any positive quantities. Then
Since and vanish for , and the second differential coefficient is always positive, must be positive except when . Therefore, if , etc. have similar definitions,
Let , , etc. be the probability-coefficients of the original ensembles, and that of the ensemble formed by combining them; and let , , etc. be the numbers of systems in the original ensembles. It is evident that we shall have
| (445) |
| (446) |
| (447) |
| (448) |
If we set
| (449) |
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