< Page:Elementary Principles in Statistical Mechanics (1902).djvu
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OF THE ENERGIES OF A SYSTEM.
97
That is, is the same function of , as of .
where the variables are connected by the equation (300). The maximum value of is therefore characterized by the equation
The values of and determined by this maximum we shall distinguish by accents, and mark the corresponding values of functions of and in the same way. Now we have by Taylor's theorem
If the approximation is sufficient without going beyond the quadratic terms, since by (300)
we may write
where the limits have been made for analytical simplicity. This is allowable when the quantity in the square brackets has a very large negative value, since the part of the integral
When is large, approximate formulae will be more available. It will be sufficient to indicate the method proposed, without precise discussion of the limits of its applicability or of the degree of its approximation. For the value of corresponding to any given , we have
| (308) |
| (309) |
| (310) |
| (311) |
| (312) |
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