< Page:Elementary Principles in Statistical Mechanics (1902).djvu
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92
CERTAIN IMPORTANT FUNCTIONS
The value of may also be put in the form
Now we may determine for from (279) where the limits are expressed by (281), and for from (284) taking the limits from (283). The two integrals thus determined are evidently identical, and we have
i. e., varies as . We may therefore set
where is a constant, at least for fixed values of the internal coördinates.
where
Having thus determined the value of the constant , we may
| (284) |
| (285) |
| (286) |
To determine this constant, let us consider the case of a canonical distribution, for which we have
Substituting this value, and that of from (286), we get
| (287) |
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